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Volume 8, Issue 1

ISAJ Newsletter - Volume 8, Issue 1 (August 2023)

The August 2023 issue explores thermoelectric energy harvesting for converting waste heat to electricity using solid-state devices, presents breakthrough research on enhancing magnesium formability through grain refinement for lightweight automotive applications, and reports on the 13th ISAJ Annual Symposium celebrating 75 years of India's independence.

Newsletter Highlights

Key Insights

Important takeaways and highlights from this issue

Thermoelectric Revolution.
TEG devices achieve 5-15% efficiency converting waste heat to electricity, with materials like SnSe reaching ZT=2.6 for Mars rovers to IoT devices
Magnesium Lightweight Solution.
10% vehicle weight reduction yields 6-8% fuel economy improvement - magnesium is 75% lighter than steel and 33% lighter than aluminum
Grain Refinement Breakthrough.
Reducing magnesium grain size from 88μm to 4.8μm eliminates fracture during 50% compression by suppressing twinning and enhancing slip
75th Independence Anniversary.
13th symposium celebrates India's 75 years of independence and 70 years of diplomatic relations with Japan at Embassy of India, Tokyo
Lifetime Achievement Award.
Prof. Atsushi Suzuki (Yokohama National University) honored for bridging India-Japan research collaborations in science and technology

Article Summaries

Below you'll find condensed summaries from our newsletter articles. To explore complete research details, figures, and references, view the full newsletter.

From Editor’s Desk

Greetings and a warm welcome to this issue of ISAJ Newsletter in 2023! We apologize for our silence since our issue in the last year.

In this issue, we present you with two research articles and event report on 13th Annual ISAJ Symposium-2022. The Research articles are on thermoelectric energy harvesting and room temperature formability of pure magnesium by grain refinement. This issue also contains pictures of our 13th annual symposium held near the end of last year.

Under the Research Spotlight section, we present you an article discussing the concept, challenges and technologies innovations in the field of thermoelectric energy harvesting. This topic is of utmost importance today for environmental conservation. The second research article on room temperature formability of pure magnesium summarizes experimental investigation of grain size impacts on deformation twinning, dislocation slip and grain boundary sliding.

ISAJ organized its 13th Annual Symposium on November 18 (Fri), 2022 in the main auditorium of Embassy of India, Tokyo. The symposium theme was “Frontiers of Materials, Life & Earth Sciences and Beyond”. There were about 90 participants, including 12 plenary speakers, 8 invited speakers and 47 poster presenters.

Research Spotlight: Thermoelectric Energy Harvesting - Concept, Challenges, and Technology

By Dr. Swapnil Ghodke, Center for Low-temperature Plasma Sciences (cLPS), Nagoya University

Introduction

Electrical energy plays an essential part in modern human society. Energy is generated by consuming non-renewable resources, which are also responsible for releasing greenhouse gases into the atmosphere. The imbalance in demand and supply of these limited energy resources forecasts a global energy crisis for future generations.

Thermoelectric generators (TEGs) are solid-state devices that can convert waste heat into useful electrical energy without any moving mechanical parts or fluids, emphasized as one of the potential technologies to reduce the carbon footprint and utilize energy resources more efficiently.

The Seebeck Effect Concept

When a temperature difference is applied across a substance that easily conducts electricity, such as a metal or semiconductor, a voltage (thermal electromotive force) is generated. The thermoelectric effect represents the mutual influence of thermal and electrical energy.

The efficiency of energy conversion in TEGs is directly proportional to the dimensionless figure-of-merit ZT = S²σT/κ, where:

  • S: Seebeck coefficient
  • σ: Electrical conductivity
  • T: Absolute temperature
  • κ: Thermal conductivity
High-Performance Materials Challenge

A high-performance thermoelectric material must be a good conductor of electricity and a poor conductor of heat - a challenging combination since these properties are typically coupled. Strategies for improvement include:

  • Grain boundary scattering
  • Nanostructuring
  • Composite effects
  • Quantum dot superlattices
  • Nanoporous structures

State-of-art materials with ZT > 1:

  • SnSe: ZT = 2.6
  • PbTe: ZT ~ 1.8
  • BiSbTe: ZT ~ 1.86
  • Cu₂Se: ZT > 2
  • Mg₂Si: ZT ~ 1.3
Applications: From Mars to Wearables

Space Exploration: NASA utilized TEGs in radioisotope thermoelectric generators for deep space missions and Mars rovers since the 1970s.

Automotive Industry: BMW and others testing TEGs for exhaust heat recovery.

IoT and Wearables: Battery-free devices powered by human body heat for digital watches, health monitoring patches, and autonomous sensors.

The growth of IoT devices has brought TEGs into daily life applications where human body heat generates power for wearable devices. These autonomous power sources for sensors generally do not require large amounts of power and can be sustained from ambient sources.

Research Highlight: Enhancement of Room-Temperature Formability of Pure Magnesium by Grain Refinement

By Dr. Elango Chandiran, National Institute for Materials Science (NIMS), Japan

The Lightweight Challenge

Increased greenhouse gas emissions contribute to climate change. Vehicle weight reduction by 10% can lead to 6-8% improvement in fuel economy. Among automotive materials, magnesium offers exceptional promise:

  • 75% lighter than steel
  • 33% lighter than aluminum
  • High specific strength and damping capacity

However, room-temperature formability remains inferior to aluminum due to magnesium’s hexagonal crystal structure having only two independent slip systems at room temperature, insufficient for continuous deformation.

Grain Refinement Solution

Commercially pure magnesium (99.96%) was extruded at temperatures between 100-400°C. Results showed:

  • Grain size decreased with lower extrusion temperature
  • Sample extruded at 160°C: Fine grains
  • Sample extruded at 350°C: Larger grains
Mechanical Testing Results

Compression testing revealed dramatic differences:

88 μm grain size:

  • Yield plateau region observed
  • Rapid strain hardening
  • Early fracture

4.8 μm grain size:

  • No plateau region
  • No fracture even after 50% compression
  • Enhanced compressibility
Deformation Mechanism Changes

Microstructural analysis using SEM and EBSD revealed:

Coarse grains (88 μm):

  • Dominant deformation twinning
  • Limited slip traces
  • Minimal grain boundary sliding

Fine grains (4.8 μm):

  • Suppressed twinning
  • Dominant dislocation slip
  • Enhanced grain boundary sliding

The refinement of grain size by extrusion at lower temperatures effectively realizes higher compressibility and formability of pure magnesium by changing the dominant deformation mechanism from twinning to slip.

Event Report: 13th ISAJ Annual Symposium 2022

The 13th ISAJ Annual Symposium on “Frontiers of Materials, Life, & Earth Sciences and Beyond” was held November 18, 2022, at the Main Auditorium, Embassy of India, Tokyo.

Special Commemorations
  • 75th anniversary of India’s independence
  • 70th anniversary of India-Japan diplomatic relations
Opening Ceremony
  • Welcome Address: Dr. Sunil Kaul, Chairman ISAJ
  • Inaugural Address: H.E. Mr. Sibi George, Ambassador of India to Japan
    • Emphasized three India-Japan joint laboratories in ICT
    • Highlighted collaboration in digital technologies, startups, climate change
Lifetime Achievement Award

Professor Atsushi Suzuki (Yokohama National University) received the ISAJ Lifetime Achievement Award 2022 for “Bridging between India and Japan researchers to strengthen research collaborations and co-operations in science and technology.”

Scientific Program
  • 12 plenary talks
  • 8 invited talks
  • 47 poster presentations
  • 5 oral presentations by young researchers
  • 90 participants from diverse nationalities (India, Japan, Italy, France, Ukraine, Indonesia)
Research Topics Covered

Wide-ranging topics including:

  • Carbon dots
  • Earth system modeling
  • Tissue engineering
  • Pandemic prediction
  • Solar cells
  • Ni-based superalloys
  • Smart hydrogels
  • Engineered phage capsids
Best Poster Awards

Winners (20,000 yen each):

  • Ms. Vanshita Sharma (Toyama Prefectural University)
  • Dr. Barun Kumar Barman (NIMS)
  • Dr. Seema Choudhury (High Energy Accelerator Research Organization)
Post-Symposium Survey

Participants expressed strong enthusiasm with suggestions for future improvements. Survey results showed high satisfaction with the scientific quality and organization of the event.

The symposium successfully brought together researchers from prestigious institutions including NIMS, JAMSTEC, Yokohama National University, JAIST, Tohoku University, IIT Delhi, RIHN, Tokyo Institute of Technology, University of Tokyo, University of Tsukuba, AIST, and others.

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ISAJ Newsletter - Volume 8, Issue 1 (August 2023) Cover

Newsletter Details

Volume 8, Issue 1

August 2023

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Editorial Team

  • Dr. Swapnil Ghodke

    Nagoya University

  • Dr. Mahendra Kumar Pal

    Indian Institute of Technology (BHU), Varanasi

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